The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 19, 2017

Filed:

Feb. 03, 2016
Applicant:

Shin-etsu Chemical Co., Ltd., Tokyo, JP;

Inventors:

Yuki Miyake, Joetsu, JP;

Takeshi Kinsho, Joetsu, JP;

Miyoshi Yamashita, Joetsu, JP;

Naoki Ishibashi, Joetsu, JP;

Yusuke Nagae, Joetsu, JP;

Akihiro Baba, Joetsu, JP;

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 17/266 (2006.01); C07C 17/269 (2006.01); C07C 2/86 (2006.01); C07C 29/10 (2006.01); C07C 29/32 (2006.01); C07C 41/48 (2006.01); C07C 45/26 (2006.01); C07C 45/51 (2006.01); C07C 67/08 (2006.01); C07C 67/40 (2006.01); C07D 309/12 (2006.01);
U.S. Cl.
CPC ...
C07D 309/12 (2013.01); C07C 2/861 (2013.01); C07C 17/266 (2013.01); C07C 17/269 (2013.01); C07C 29/103 (2013.01); C07C 29/32 (2013.01); C07C 41/48 (2013.01); C07C 45/26 (2013.01); C07C 45/515 (2013.01); C07C 67/08 (2013.01); C07C 67/40 (2013.01); C07B 2200/09 (2013.01); C07C 2527/122 (2013.01);
Abstract

Provided are a method for efficiently producing an asymmetric conjugated diyne from an inexpensive and safe alternative compound to hydroxylamine hydrochloride and a method for producing a Z,Z-conjugated diene compound from the asymmetric conjugated diyne compound thus obtained. More specifically, provided is a method for producing an asymmetric conjugated diyne compound comprising a step of subjecting a terminal alkyne compound (1): HC≡C—Z—Yto a coupling reaction with an alkynyl halide (2): Y—Z—C≡C—X by using sodium borohydride in water and an organic solvent in the presence of a copper catalyst and a base to obtain the asymmetric conjugated diyne compound (3): Y—Z—C≡C—C≡C—Z—Y. In addition, provided is a method for producing a Z,Z-conjugated diene compound by reducing the resulting asymmetric conjugated diyne compound, or the like.


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