The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 19, 2017

Filed:

Jun. 16, 2014
Applicant:

University of Cincinnati, Cincinnati, OH (US);

Inventors:

Vesselin N. Shanov, Cincinnati, OH (US);

Andrew Gorton, Albany, NY (US);

Yeo-Heung Yun, Greensboro, NC (US);

Mark J. Schulz, West Chester, OH (US);

Assignee:

Other;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 21/18 (2006.01); C01B 32/162 (2017.01); C01B 31/02 (2006.01); B01J 23/40 (2006.01); B01J 23/63 (2006.01); B01J 23/74 (2006.01); B01J 23/83 (2006.01); B01J 35/00 (2006.01); B01J 37/02 (2006.01); B01J 37/08 (2006.01); B01J 37/34 (2006.01); B82Y 30/00 (2011.01); B82Y 40/00 (2011.01); D01F 9/12 (2006.01); D01F 9/127 (2006.01);
U.S. Cl.
CPC ...
C01B 31/0233 (2013.01); B01J 21/185 (2013.01); B01J 23/40 (2013.01); B01J 23/63 (2013.01); B01J 23/74 (2013.01); B01J 23/83 (2013.01); B01J 35/0013 (2013.01); B01J 37/0217 (2013.01); B01J 37/0221 (2013.01); B01J 37/0226 (2013.01); B01J 37/0238 (2013.01); B01J 37/0244 (2013.01); B01J 37/08 (2013.01); B01J 37/088 (2013.01); B01J 37/348 (2013.01); B01J 37/349 (2013.01); B82Y 30/00 (2013.01); B82Y 40/00 (2013.01); C01B 32/162 (2017.08); D01F 9/12 (2013.01); D01F 9/127 (2013.01); D01F 9/1273 (2013.01); C01B 2202/06 (2013.01); C01B 2202/08 (2013.01); C01B 2202/34 (2013.01); Y10S 977/752 (2013.01);
Abstract

A method of forming a carbon nanotube array substrate is disclosed. One embodiment comprises depositing a composite catalyst layer on the substrate, oxidizing the composite catalyst layer, reducing the oxidized composite catalyst layer, and growing the array on the composite catalyst layer. The composite catalyst layer may comprise a group VIII element and a non-catalytic element deposited onto the substrate from an alloy. In another embodiment, the composite catalyst layer comprises alternating layers of iron and a lanthanide, preferably gadolinium or lanthanum. The composite catalyst layer may be reused to grow multiple carbon nanotube arrays without additional processing of the substrate. The method may comprise bulk synthesis by forming carbon nanotubes on a plurality of particulate substrates having a composite catalyst layer comprising the group VIII element and the non-catalytic element. In another embodiment, the composite catalyst layer is deposited on both sides of the substrate.


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