The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 21, 2017

Filed:

Apr. 24, 2013
Applicant:

Versalis S.p.a., San Donato Milanese, IT;

Inventors:

Andrea Vallieri, Bologna, IT;

Marianna Zinna, Ravenna, IT;

Costantino Perretta, Ferrara, IT;

Assignee:

Versalis S.p.A., San Donato Milanese, IT;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 136/06 (2006.01); B60C 1/00 (2006.01); C08F 36/06 (2006.01); C08K 3/04 (2006.01); C08K 3/36 (2006.01);
U.S. Cl.
CPC ...
C08F 136/06 (2013.01); B60C 1/00 (2013.01); C08F 36/06 (2013.01); C08K 3/04 (2013.01); C08K 3/36 (2013.01);
Abstract

A process for the preparation of branched polybutadiene having a high content of 1,4-cis units which comprises polymerizing butadiene in the presence of at least one organic solvent, and in the presence of: a) a catalytic system prepared in situ including: (a) at least one neodymium carboxylate, (a) at least one alkyl compound of aluminum, (A) at least one alkyl compound of aluminum containing at least one halogen atom, and b) at least one organic ester containing at least one halogen atom. Said branched polybutadiene having a high content of 1,4-cis units, depending on the branching degree and molecular weight distribution, can be advantageously used in various applications ranging from the modification of plastic materials [production, for example, of high impact polystyrene (HIPS)] to the production of tires, in particular the production of treads and/or of sidewalls of tires.


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