The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 21, 2017

Filed:

Jan. 28, 2016
Applicant:

Eastman Chemical Company, Kingsport, TN (US);

Inventors:

Venkata Bharat Boppana, Johnson City, TN (US);

Kenneth Wayne Hampton, Jr., Gilmer, TX (US);

Zhufang Liu, Kingsport, TN (US);

Charles Edwan Sumner, Jr., Kingsport, TN (US);

Gerald C. Tustin, Kingsport, TN (US);

Guy Ralph Steinmetz, Kingsport, TN (US);

Melissa Page Steffey, Nickelsville, VA (US);

Assignee:

Eastman Chemical Company, Kingsport, TN (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 23/42 (2006.01); B01J 23/44 (2006.01); C07C 45/00 (2006.01); C07C 45/72 (2006.01); B01J 21/06 (2006.01); B01J 37/02 (2006.01); B01J 37/16 (2006.01); B01J 37/18 (2006.01); B01J 35/00 (2006.01);
U.S. Cl.
CPC ...
C07C 45/72 (2013.01); B01J 21/063 (2013.01); B01J 23/44 (2013.01); B01J 35/0013 (2013.01); B01J 37/0221 (2013.01); B01J 37/0236 (2013.01); B01J 37/16 (2013.01); B01J 37/18 (2013.01);
Abstract

Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.


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