The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 31, 2017

Filed:

Jan. 22, 2016
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Christine N. Elia, Bridgewater, NJ (US);

Shifang L. Luo, Annandale, NJ (US);

Hari Nair, Somerville, NJ (US);

Wenyih F. Lai, Bridgewater, NJ (US);

Robert G. Tinger, Friendswood, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 6/12 (2006.01); C07C 4/18 (2006.01); B01J 29/80 (2006.01); B01J 35/10 (2006.01); B01J 29/22 (2006.01); B01J 29/24 (2006.01); B01J 29/44 (2006.01); B01J 29/46 (2006.01); B01J 8/04 (2006.01); B01J 37/18 (2006.01); B01J 29/67 (2006.01); B01J 29/68 (2006.01); B01J 29/74 (2006.01); B01J 29/76 (2006.01); B01J 35/00 (2006.01); B01J 35/02 (2006.01); C01B 39/26 (2006.01);
U.S. Cl.
CPC ...
B01J 29/80 (2013.01); B01J 8/04 (2013.01); B01J 29/22 (2013.01); B01J 29/24 (2013.01); B01J 29/44 (2013.01); B01J 29/46 (2013.01); B01J 29/67 (2013.01); B01J 29/68 (2013.01); B01J 29/74 (2013.01); B01J 29/7446 (2013.01); B01J 29/7453 (2013.01); B01J 29/7461 (2013.01); B01J 29/7476 (2013.01); B01J 29/7484 (2013.01); B01J 29/7492 (2013.01); B01J 29/76 (2013.01); B01J 29/7646 (2013.01); B01J 29/7653 (2013.01); B01J 29/7661 (2013.01); B01J 29/7676 (2013.01); B01J 29/7684 (2013.01); B01J 29/7692 (2013.01); B01J 35/002 (2013.01); B01J 35/023 (2013.01); B01J 35/108 (2013.01); B01J 35/1014 (2013.01); B01J 35/1019 (2013.01); B01J 35/1023 (2013.01); B01J 35/1033 (2013.01); B01J 35/1052 (2013.01); B01J 37/18 (2013.01); C01B 39/265 (2013.01); C07C 4/18 (2013.01); C07C 6/126 (2013.01); B01J 2208/027 (2013.01); B01J 2229/186 (2013.01); B01J 2229/42 (2013.01); C07C 2521/04 (2013.01); C07C 2529/18 (2013.01); C07C 2529/22 (2013.01); C07C 2529/24 (2013.01); C07C 2529/40 (2013.01); C07C 2529/44 (2013.01); C07C 2529/46 (2013.01); C07C 2529/80 (2013.01); C07C 2529/87 (2013.01); Y02P 20/52 (2015.11);
Abstract

Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.


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