The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 03, 2017

Filed:

Apr. 18, 2014
Applicant:

The United States of America, As Represented BY the Secretary of the Air Force, Washington, DC (US);

Inventors:

Raymond Campos, Dallas, TX (US);

Andrew Guenthner, Lancaster, CA (US);

Timothy Haddad, Lancaster, CA (US);

Joseph M. Mabry, Quartz Hill, CA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B32B 5/16 (2006.01); C08K 5/02 (2006.01); C09C 3/12 (2006.01); C09C 3/06 (2006.01); C08K 9/12 (2006.01); C08K 7/26 (2006.01); C09C 1/30 (2006.01); C08K 5/54 (2006.01); C08K 9/04 (2006.01);
U.S. Cl.
CPC ...
C09C 3/12 (2013.01); C08K 5/02 (2013.01); C08K 5/5406 (2013.01); C08K 7/26 (2013.01); C08K 9/04 (2013.01); C08K 9/12 (2013.01); C09C 1/3081 (2013.01); C09C 3/063 (2013.01); C01P 2002/82 (2013.01); C01P 2004/50 (2013.01); Y10T 428/2991 (2015.01); Y10T 428/2995 (2015.01);
Abstract

Treated, mesoporous aggregates comprising a plurality of coated particles that comprise an inorganic oxide core having a surface area of about 50 to about 500 square meters per gram and a shell or coating consisting of an array of fluoroalkyl molecular chains covalently bonded to the core at a density of at least one chain per square nanometer. The aggregates are formed by the chemical attachment of fluoroalkyl-alkylsilanes after exposure to an alkylamine and followed by an extraction to remove any unbound organic material. The dense packing of molecular chains in the fluoroalkyl shell combined with a mesoporous structure imparts a very low surface energy, a very high specific surface area, and surface texture over a wide range of length scales. Such features are highly desirable for the creation of, for example, superhydrophobic and superoleophobic surfaces, separation media, and release films.


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