The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 03, 2017

Filed:

Oct. 05, 2012
Applicant:

The University of Akron, Akron, OH (US);

Inventors:

Coleen Pugh, Akron, OH (US);

Guillermina Garcia, Copley, OH (US);

Assignee:

The University of Akron, Akron, OH (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 83/00 (2006.01); C08F 26/06 (2006.01); C08F 220/40 (2006.01);
U.S. Cl.
CPC ...
C08F 26/06 (2013.01); C08F 220/40 (2013.01); C08G 83/005 (2013.01); C08F 2438/01 (2013.01); C08F 2438/02 (2013.01); C08F 2438/03 (2013.01);
Abstract

A method for the production of hyperbranched polyacrylates includes the step of reacting acrylic inimers through controlled living polymerization in aqueous conditions. The inimers may have the formula: Wherein X is a halogen, a thiocarbonylthio or nitroxide group, and R is hydrogen, methyl, dodecyl, and groups containing mesogenin substituents, fluorocarbon substituents, siloxane substituents and oxyethylene substituents. In particular, the aqueous condition is emulsion or miniemulsion. The polymerization may be reverse ATRP, SN&RI and AGET polymerization or RAFT polymerization (with thiocarbonylthio X groups) or nitroxide mediated polyeization (with nitroxide X groups).


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