The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 26, 2017

Filed:

Dec. 01, 2015
Applicant:

Belenos Clean Power Holding Ag, Biel/Bienne, CH;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 311/15 (2006.01); C07C 311/48 (2006.01); H01M 10/0525 (2010.01); H01M 10/054 (2010.01); H01M 10/0565 (2010.01); H01M 10/0568 (2010.01); C08F 212/14 (2006.01); C08F 220/14 (2006.01); H01M 4/04 (2006.01); H01M 4/13 (2010.01); H01M 4/139 (2010.01); H01M 4/36 (2006.01); H01M 4/62 (2006.01); H01M 4/02 (2006.01);
U.S. Cl.
CPC ...
C07C 311/15 (2013.01); C07C 311/48 (2013.01); C08F 212/14 (2013.01); C08F 220/14 (2013.01); H01M 4/0402 (2013.01); H01M 4/0483 (2013.01); H01M 4/13 (2013.01); H01M 4/139 (2013.01); H01M 4/364 (2013.01); H01M 4/625 (2013.01); H01M 10/054 (2013.01); H01M 10/0525 (2013.01); H01M 10/0565 (2013.01); H01M 10/0568 (2013.01); H01M 2004/027 (2013.01); H01M 2004/028 (2013.01); H01M 2300/0082 (2013.01);
Abstract

A specific cross-linker, an alkaline metal bis(styrenesulfonyl)imide monomer, is used in the synthesis of single ionic conductive copolymers that are non-fluorinated and non-PEO based. Such copolymers meet the security and costs requirements to be used as solid polymers electrolytes (SPE). They are promising alternatives to standard liquid electrolytes in alkaline metal-ion batteries because of their improved security and inflammability properties. The copolymers described are either polyvinylsulfonates or acrylate vinylsulfonate block-copolymers. Preferred acrylate monomers are methacrylates and preferred vinylsulfonates are styrene sulfonates. The copolymer is prepared by radical polymerization of the vinyl sulfonate and the cross-linker and optionally the acrylate, in particular radical photopolymerization using a functionalized bis(acyl)phosphane oxide (BAPO) as photoinitiator. Also described is the use of such copolymer as solid polymer electrolyte in a lithium ion battery.


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