The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 08, 2017

Filed:

May. 14, 2013
Applicant:

Halliburton Energy Services, Inc., Houston, TX (US);

Inventors:

Enrique Antonio Reyes, Houston, TX (US);

Alyssa Lynn Smith, Houston, TX (US);

Aaron M. Beuterbaugh, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C09K 8/72 (2006.01); C09K 8/74 (2006.01);
U.S. Cl.
CPC ...
C09K 8/72 (2013.01); C09K 8/74 (2013.01);
Abstract

Acidizing operations in subterranean formations that contain both a siliceous material and a source of calcium ions can often be problematic due to the generation of calcium-containing precipitates, particularly calcium fluoride. Methods for treating a subterranean formation can comprise: providing a treatment fluid having a pH ranging between about 1 and about 4.5 and comprising a chelating agent, hydrofluoric acid or a hydrofluoric acid-generating compound, and a compound having two or more quaternized amine groups; introducing the treatment fluid into a subterranean formation containing a siliceous material and a source of calcium ions; dissolving at least a portion of the siliceous material in the subterranean formation with the hydrofluoric acid or the hydrofluoric acid-generating compound; and complexing at least a portion of the calcium ions in the subterranean formation with the chelating agent.


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