The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 01, 2017

Filed:

Nov. 14, 2014
Applicant:

Sabic Global Technologies B.v., Bergen op Zoom, NL;

Inventors:

Jordi Calveras, Evansville, IN (US);

Thomas L. Evans, Mount Vernon, IN (US);

Assignee:

SABIC Global Technologies B.V., Bergen op Zoom, NL;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
G01N 33/44 (2006.01); C08G 64/14 (2006.01);
U.S. Cl.
CPC ...
G01N 33/442 (2013.01); C08G 64/14 (2013.01);
Abstract

Methods for screening molecules or moieties for their ability to crosslink are disclosed. An aromatic carbonate, aromatic ester, or aliphatic ester group is attached to the molecule to mimic the presence of a polymer. A solution of the modified molecule is irradiated, and the first-order kinetic rate constant is measured. If the rate constant is high enough or a threshold amount of the molecule is consumed, a polymer is synthesized using the molecule/moiety as an endcap or co-monomer. The polymer is irradiated, and the increase in crosslink density and the gel formation percentage are determined. These parameters, if high enough, indicate the suitability of the molecule/moiety to act as a crosslinking agent, particularly for polycarbonates. Alternatively, the molecule/moiety may be identified as suitable solely by its first-order kinetic rate constant.


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