The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 25, 2017

Filed:

Dec. 30, 2014
Applicant:

Eastman Chemical Company, Kingsport, TN (US);

Inventors:

Andrew James Vetter, Kingsport, TN (US);

Jonathan Michael Penney, Gray, TN (US);

David William Norman, Cary, NC (US);

Assignee:

Eastman Chemical Company, Kingsport, TN (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 45/00 (2006.01); C07C 45/49 (2006.01); B01J 31/24 (2006.01); C07C 29/16 (2006.01); C07C 45/50 (2006.01); C07C 51/12 (2006.01);
U.S. Cl.
CPC ...
C07C 45/49 (2013.01); B01J 31/2409 (2013.01); C07C 29/16 (2013.01); C07C 45/50 (2013.01); C07C 51/12 (2013.01); B01J 2231/34 (2013.01); B01J 2531/845 (2013.01);
Abstract

Disclosed is a process for the reductive carbonylation of a low molecular weight alcohol to produce the homologous aldehyde and/or alcohol. The process includes conducting the reaction to produce the aldehyde in the presence of a catalyst complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4 with a phosphine ligand. A ruthenium co-catalyst is used in the production of the homologous alcohol. The reductive carbonylation reaction does not require an additional iodide promoter and produces a crude reductive carbonylation product substantially free of methyl iodide.


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