The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 18, 2017

Filed:

Oct. 24, 2012
Applicants:

China Petroleum & Chemical Corporation, Beijing, CN;

Fushun Research Institute of Petroleum and Petrochemicals, Sinopec, Fushun, Liaoning, CN;

Inventors:

Shumei Zhang, Liaoning, CN;

Kai Qiao, Liaoning, CN;

Ming Chen, Liaoning, CN;

Qingtong Zhai, Liaoning, CN;

Changxin Guo, Liaoning, CN;

Chunmei Wang, Liaoning, CN;

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 1/22 (2006.01); C07C 1/20 (2006.01); B01J 29/035 (2006.01); B01J 29/06 (2006.01); B01J 35/10 (2006.01);
U.S. Cl.
CPC ...
C07C 1/22 (2013.01); B01J 29/035 (2013.01); B01J 29/0354 (2013.01); B01J 29/0356 (2013.01); B01J 29/06 (2013.01); B01J 35/1019 (2013.01); B01J 35/1038 (2013.01); B01J 35/1042 (2013.01); C07C 1/20 (2013.01); B01J 2029/062 (2013.01); B01J 2229/186 (2013.01); C07C 2521/12 (2013.01); C07C 2529/035 (2013.01); C07C 2529/06 (2013.01);
Abstract

Disclosed is a catalyst for preparing isobutene by dissociation of methyl tert-butyl ether, the catalyst comprising amorphous silica alumina and a silicalite-1 molecular sieve, wherein the total IR acid amount of weak acids in the catalyst is in a range from 0.020 to 0.080 mmol/g, and the ratio of B acid/L acid of the weak acids is in a range from 2.5:1 to 4.0:1. Also provided is a method of preparing the catalyst and the use thereof. The catalyst has a high selectivity with respect to isobutene, and high conversion of methyl tert-butyl ether, and can also effectively inhibit formation of the by-product dimethyl ether.


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