The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 04, 2017

Filed:

Mar. 23, 2015
Applicant:

Wacker Chemie Ag, Munich, DE;

Inventors:

Peter Gigler, Dachau, DE;

Maria Leute, Burghausen, DE;

Jürgen Stohrer, Pullach, DE;

Assignee:

Wacker Chemie AG, Munich, DE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 67/343 (2006.01); C07C 67/10 (2006.01); C07C 51/09 (2006.01); B01J 31/22 (2006.01); C07C 51/353 (2006.01);
U.S. Cl.
CPC ...
C07C 67/343 (2013.01); B01J 31/2208 (2013.01); C07C 51/09 (2013.01); C07C 51/353 (2013.01); C07C 67/10 (2013.01); B01J 2231/40 (2013.01); B01J 2531/821 (2013.01);
Abstract

The invention relates to a process for transvinylation of a carboxylic acid feedstock with a vinyl ester feedstock to obtain a vinyl ester product and the corresponding acid of the vinyl ester feedstock in the presence of one or more ruthenium catalysts, wherein a) the vinyl ester feedstock, the carboxylic acid feedstock and a ruthenium catalyst are fed to the reactor, and b) the transvinylation reaction is carried out, characterized in that a carbonyl-free Ru(III) carboxylate is used as the ruthenium catalyst and in that no carbon monoxide is supplied, c) the reaction is carried out at a temperature of 110 to 170° C., d) upon completion of the transvinylation reaction, the vinyl ester feedstock and the corresponding acid are separated from the reaction mixture by distillation, e) the vinyl ester product is separated by distillation from the bottom product of the distillation, and f) the remaining reaction mixture is recycled into the reactor.


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