The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 27, 2017

Filed:

Sep. 27, 2013
Applicant:

Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu Province, CN;

Inventors:

Feng Shi, Lanzhou, CN;

Xinjiang Cui, Lanzhou, CN;

Hangkong Yuan, Lanzhou, CN;

Yan Zhang, Lanzhou, CN;

Youquan Deng, Lanzhou, CN;

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07D 295/023 (2006.01); C07D 295/03 (2006.01); C07D 295/033 (2006.01); C07C 209/60 (2006.01); C07C 209/68 (2006.01); C07C 211/46 (2006.01); C07C 211/48 (2006.01); C07C 211/55 (2006.01); C07C 213/08 (2006.01); B01J 23/72 (2006.01); C07D 211/14 (2006.01); C07C 209/26 (2006.01); C07C 209/36 (2006.01); C07C 209/48 (2006.01); C07C 213/02 (2006.01);
U.S. Cl.
CPC ...
C07D 295/03 (2013.01); C07C 209/26 (2013.01); C07C 209/36 (2013.01); C07C 209/48 (2013.01); C07C 213/02 (2013.01); C07C 213/08 (2013.01); C07D 211/14 (2013.01);
Abstract

A process for producing N-methyl or N,N-dimethyl amines, which comprises using amine compound, nitro-containing compound or nitrile compound as a starting material, carbon dioxide as a methylating agent and hydrogen gas as a reducing agent, and allowing them to react in a sealed reactor for 6 to 48 h in a reaction medium at a reaction temperature of 80 to 180 ° C. in the presence of a composite catalyst, so as to provide N-methyl or N,N-dimethyl amines. The process of the present invention is simple and under relative mild reaction conditions. By means of the process of the invention, the target products can be prepared at low cost with a high yield. The catalysts used have a high catalytic activity and can be separated from the reaction system simply and reused. Furthermore, the whole process of the present invention is environmental-friendly and facilitates the cycling use of carbon dioxide.


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