The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 20, 2017

Filed:

Jun. 03, 2014
Applicant:

Mitsui Chemicals, Inc., Tokyo, JP;

Inventor:

Masayasu Ishibashi, Yamaguchi, JP;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 1/24 (2006.01); B01J 21/04 (2006.01); B01J 21/08 (2006.01); B01J 35/10 (2006.01); B01J 21/12 (2006.01); B01J 35/02 (2006.01);
U.S. Cl.
CPC ...
C07C 1/24 (2013.01); B01J 21/04 (2013.01); B01J 21/08 (2013.01); B01J 21/12 (2013.01); B01J 35/023 (2013.01); B01J 35/1061 (2013.01); C07C 2521/12 (2013.01); Y02P 20/52 (2015.11);
Abstract

An object of the present invention is to provide a method of producing a corresponding olefin such as propylene with a high activity and a high selectivity even in a high LHSV range by an intramolecular dehydration reaction of an alcohol such as isopropyl alcohol. The present invention provides a method of producing an olefin represented by General Formula (II) below from an alcohol represented by General Formula (I) below, which method uses, as a dehydration catalyst, a chemically treated silica gel (X) in which an aluminum compound is supported onto a silica gel (A) with an average fine pore diameter of 10 to 50 nm in the amount of 1,000 to 10,000 ppm by weight in terms of aluminum element. (In General Formulae (I) and (II), Ris selected from alkyl groups of 1 to 5 carbon atoms and Ris selected from a hydrogen atom and alkyl groups of 1 to 5 carbon atoms.)


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