The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 13, 2017

Filed:

Dec. 18, 2014
Applicant:

Ecolab Usa Inc., St. Paul, MN (US);

Inventors:

Amy M. Tseng, Woodridge, IL (US);

Brian V. Jenkins, Warrenville, IL (US);

Robert M. Mack, Milwaukie, OR (US);

Assignee:

ECOLAB USA INC., St. Paul, MN (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
G01N 21/25 (2006.01); G01N 31/22 (2006.01); G01N 21/80 (2006.01);
U.S. Cl.
CPC ...
G01N 21/255 (2013.01); G01N 31/22 (2013.01); G01N 21/80 (2013.01);
Abstract

A method of detecting and measuring the presence of ammonium fluoride in a buffered oxide etchant ('BOE') composition is provided. The method comprises contacting a BOE composition with a chromogenic agent selected from bromothymol blue, Eosin-Bluish, indophenol blue, bromocresol green, orthophthaldialdehyde, tetraphenylprophyrin, acridine orange, naphthalene-2,3-dicarboxaldehyde, 2-mercaptoethanol, n-acetylcysteine, luminal, bromocresol purple, or bromophenol blue and at least one of sodium hydroxide, ammonium nitrate, ammonium chloride, tartaric acid, octylphenoxypolyethoxyethanol, Triton X-100, borate buffer, sodium chloride, sodium tetra borate decahydrate, sodium sulfite, and Brij35 to form a treated BOE composition, the treated BOE composition having spectroscopic properties resulting from the contacting that correlate with the amount of ammonium fluoride in the treated BOE composition, performing a spectrometric measurement of the spectroscopic properties of the treated BOE composition, and comparing the spectrometric measurement to pre-determined values to identify the amount of ammonium fluoride in the BOE composition.


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