The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 09, 2017

Filed:

Jun. 24, 2014
Applicant:

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

Daniel J. Arriola, Midland, MI (US);

Brad C. Bailey, Midland, MI (US);

Jerzy Klosin, Midland, MI (US);

Zenon Lysenko, Midland, MI (US);

Gordon R. Roof, Midland, MI (US);

Austin J. Smith, Saginaw, MI (US);

Assignee:

DOW GLOBAL TECHNOLOGIES LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/34 (2006.01); C08F 10/00 (2006.01); C10M 105/00 (2006.01); B01J 31/00 (2006.01); C10M 107/02 (2006.01); C10M 107/04 (2006.01); C10M 107/10 (2006.01);
U.S. Cl.
CPC ...
C07C 2/34 (2013.01); B01J 31/00 (2013.01); C08F 10/00 (2013.01); C10M 105/00 (2013.01); C10M 107/02 (2013.01); C10M 107/04 (2013.01); C10M 107/10 (2013.01); C07C 2531/22 (2013.01); C10M 2203/02 (2013.01); C10M 2205/0225 (2013.01); C10M 2205/0285 (2013.01); C10N 2220/028 (2013.01); C10N 2250/10 (2013.01); C10N 2270/00 (2013.01);
Abstract

A process to prepare a relatively inexpensive utility fluid comprises contacting together ethylene and a coordination-insertion catalyst and, optionally, an alpha-olefin, in a continuously-fed backmixed reactor zone under conditions such that a mixture of a hyperbranched oligomer and a branched oligomer is formed. The hyperbranched oligomer has an average of at least 1.5 methine carbons per oligomer molecule, and at least 40 methine carbons per one-thousand total carbons, and at least 40 percent of the methine carbons is derived from the ethylene, and the average number of carbons per molecule is from 25 to 100, and at least 25 percent of the hyperbranched oligomer molecules has a vinyl group and can be separated from the branched oligomer, which has an average number of carbons per molecule of up to 20. The coordination-insertion catalyst is characterized as having an ethylene/octene reactivity ratio up to 20 and a kinetic chain length up to 20 monomer units.


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