The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 18, 2017

Filed:

Jun. 24, 2016
Applicant:

Nanjing Tech University (Cn), Nanjing, CN;

Inventors:

Kai Guo, Nanjing, CN;

Xin Li, Nanjing, CN;

Zheng Fang, Nanjing, CN;

Kai Zhang, Nanjing, CN;

Qi Yu, Nanjing, CN;

Pingkai Ouyang, Nanjing, CN;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 201/04 (2006.01); C07D 201/06 (2006.01); C07D 223/10 (2006.01);
U.S. Cl.
CPC ...
C07D 223/10 (2013.01); Y02P 20/52 (2015.11);
Abstract

A method for preparing caprolactam by using a microreactor under Lewis acid catalysis, wherein a hydroxyl group in a cyclohexanone oxime is activated to obtain a cyclohexanone oxime sulfonates intermediate, then rearranged under Lewis acid catalysis to prepare the caprolactam. The method of this invention has a simple process and a high operation safety and selectivity, the reaction condition is mild, an efficient reaction can take place even at room temperature, the reaction time is short, the conversion of the cyclohexanone oxime can reach 100% within a short time, the selectivity of the caprolactam can reach 99%, the energy consumption is greatly reduced in the premise of maintaining a high yield, and the production cost is reduced, being an efficient and green and environmentally friendly method of for synthesizing the caprolactam.


Find Patent Forward Citations

Loading…