The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 18, 2017

Filed:

Nov. 01, 2009
Applicants:

Esmaeel Naeemi, Lynnwood, WA (US);

Mangesh Bore, Redmond, WA (US);

David G. O'connor, North Bend, WA (US);

Robert B. Nelson, Snoqualmie, WA (US);

Inventors:

Esmaeel Naeemi, Lynnwood, WA (US);

Mangesh Bore, Redmond, WA (US);

David G. O'Connor, North Bend, WA (US);

Robert B. Nelson, Snoqualmie, WA (US);

Assignee:

ASEMBLON, INC., Redmond, WA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 19/00 (2006.01); C01B 3/22 (2006.01); B01J 12/00 (2006.01); B01J 19/24 (2006.01); B01J 23/42 (2006.01); B01J 23/44 (2006.01); B01J 23/46 (2006.01); B01J 23/50 (2006.01); B01J 23/52 (2006.01); B01J 37/02 (2006.01); B01J 21/04 (2006.01); B01J 21/06 (2006.01); B01J 21/08 (2006.01); B01J 21/18 (2006.01);
U.S. Cl.
CPC ...
B01J 12/007 (2013.01); B01J 19/2485 (2013.01); B01J 23/42 (2013.01); B01J 23/44 (2013.01); B01J 23/464 (2013.01); B01J 23/50 (2013.01); B01J 23/52 (2013.01); B01J 37/0201 (2013.01); C01B 3/22 (2013.01); B01J 21/04 (2013.01); B01J 21/063 (2013.01); B01J 21/08 (2013.01); B01J 21/18 (2013.01); B01J 2219/00006 (2013.01); B01J 2219/00063 (2013.01); B01J 2219/00094 (2013.01); B01J 2219/00117 (2013.01); B01J 2219/00155 (2013.01); C01B 2203/0277 (2013.01); C01B 2203/04 (2013.01); C01B 2203/048 (2013.01); C01B 2203/107 (2013.01); C01B 2203/1023 (2013.01); C01B 2203/1041 (2013.01); C01B 2203/1064 (2013.01); C01B 2203/1082 (2013.01); C01B 2203/1217 (2013.01); C01B 2203/1288 (2013.01); C01B 2203/148 (2013.01); C01B 2203/169 (2013.01); C01B 2203/1619 (2013.01); C01B 2203/1623 (2013.01);
Abstract

There is disclosed a surprising reaction of an alkane thiol with a catalyst and heat to become dehydrogenated and form a thiophene rather than an expected desulfurization reaction to form the corresponding alkane or alkene. Moreover, there are disclosed surprising results regarding the form of a catalyst to allow a reaction of an alkane thiol to form the dehydrogenated thiophene at lower temperatures and at higher conversion percentages to allow for more efficient recovery of thiophenes to allow for recycling and reuse of thiophenes to hydrogenate to form alkane thiols. Further still, there is disclosed a set of reaction conditions and catalyst presentation that allows for recovery of usable diatomic hydrogen gas from a dehydrogenation reaction of substituted or unsubstituted cyclic thioethers to substituted or unsubstituted thiophene.


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