The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 04, 2017

Filed:

Mar. 02, 2011
Applicants:

Susan V. Olesik, Dublin, OH (US);

Joseph W. Zewe, Marion Center, PA (US);

Inventors:

Susan V. Olesik, Dublin, OH (US);

Joseph W. Zewe, Marion Center, PA (US);

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J 20/32 (2006.01); C01B 31/02 (2006.01); B01J 20/20 (2006.01); B32B 3/30 (2006.01); B01J 20/30 (2006.01); G01N 1/40 (2006.01);
U.S. Cl.
CPC ...
B01J 20/324 (2013.01); B01J 20/20 (2013.01); B01J 20/205 (2013.01); B01J 20/3057 (2013.01); B01J 20/3078 (2013.01); B32B 3/30 (2013.01); C01B 31/02 (2013.01); G01N 1/405 (2013.01); G01N 2600/00 (2013.01); Y10T 428/24802 (2015.01);
Abstract

Preparation of a molecularly imprinted carbon is described. The molecularly imprinted carbon has a surface that is imprinted on the molecular level for a specific template molecule of interest, making it highly selective for analytes corresponding to at least a portion of the template molecule. Devices including the molecularly imprinted carbon and their use in methods of detecting analytes are also described. As an example, dibutyl butylphosphonate (DBBP), a surrogate for chemical warfare agents, was used as a template molecule. Electrospun molecularly imprinted SU-8 and pyrolyzed polymer (PP) solid-phase microextraction (SPME) devices were prepared; their ability to preferentially extract DBBP from an aqueous matrix, with and without interferences present, was evaluated via comparison with non-imprinted SU-8 and PP SPME fibers. The electrospun devices demonstrated a higher selectivity for DBBP, as evidenced by their extraction time profiles. The MI-SPME fibers tested extracted at least 60% more DBBP than their non-imprinted counterparts.


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