The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 14, 2017

Filed:

May. 01, 2015
Applicant:

Wisconsin Alumni Research Foundation, Madison, WI (US);

Inventors:

Shannon S. Stahl, Madison, WI (US);

Adam B. Powell, Wexford, PA (US);

Thatcher W. Root, Madison, WI (US);

David S. Mannel, Madison, WI (US);

Maaz S. Ahmed, Middleton, WI (US);

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 67/40 (2006.01); C07C 51/235 (2006.01); B01J 23/644 (2006.01); C07D 307/68 (2006.01); C07B 33/00 (2006.01); C07B 41/08 (2006.01); B01J 37/03 (2006.01); B01J 37/16 (2006.01); B01J 23/00 (2006.01); B01J 23/58 (2006.01); B01J 23/60 (2006.01); B01J 23/62 (2006.01); B01J 23/648 (2006.01); B01J 37/02 (2006.01);
U.S. Cl.
CPC ...
C07C 51/235 (2013.01); B01J 23/002 (2013.01); B01J 23/58 (2013.01); B01J 23/60 (2013.01); B01J 23/628 (2013.01); B01J 23/6447 (2013.01); B01J 23/6484 (2013.01); B01J 37/0203 (2013.01); B01J 37/035 (2013.01); B01J 37/16 (2013.01); C07B 33/00 (2013.01); C07B 41/08 (2013.01); C07C 67/40 (2013.01); C07D 307/68 (2013.01); C07C 2101/14 (2013.01);
Abstract

Disclosed are methods for synthesizing an ester or a carboxylic acid from an organic alcohol. To form the ester one reacts, in the presence of oxygen gas, the alcohol with methanol or ethanol. This reaction occurs in the presence of a catalyst comprising palladium and a co-catalyst comprising bismuth, tellurium, lead, cerium, titanium, zinc and/or niobium (most preferably at least bismuth and tellurium). Alternatively that catalyst can be used to generate an acid from that alcohol, when water is also added to the reaction mix.


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