The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 28, 2017

Filed:

Apr. 10, 2015
Applicants:

Archer Daniels Midland Company, Decatur, IL (US);

Washington State University, Pullman, WA (US);

Inventors:

Junming Sun, Pullman, WA (US);

Changjun Liu, Pullman, WA (US);

Yong Wang, Pullman, WA (US);

Kevin Martin, Mt. Zion, IL (US);

Padmesh Venkitasubramanian, Forsyth, IL (US);

Assignee:

Archer-Daniels-Midland-Company, Decatur, IL (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 1/00 (2006.01); C07C 1/20 (2006.01); C07C 1/207 (2006.01);
U.S. Cl.
CPC ...
C07C 1/2078 (2013.01); C07C 1/207 (2013.01); C07C 2521/06 (2013.01); C07C 2523/06 (2013.01);
Abstract

A process is disclosed for converting acetic acid to propylene and isobutene as the principal hydrocarbon products made, in the presence of a catalyst and in the further presence of hydrogen. In certain embodiments, a ZnZrOmixed oxide catalyst is used for carrying out a gas phase process, and propylene is produced preferentially to isobutene by using at least a certain amount of hydrogen in the process. In some embodiments, a ZnZrOmixed oxide catalyst made by an incipient wetness impregnation method is used and is indicated to be very stable for carrying out the conversion.


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