Process for making opaque polyester film

Abstract

The invention relates to a process for making an opaque and glossy film from a thermoplastic polyester composition, comprising the steps of a) extruding the polyester composition through a slot die, and quenching to form a substantially amorphous film having a crystallinity of at most 5%; b) rapidly heating the amorphous film to a drawing temperature in the range from Tto (T+50)° C. while applying a draw ratio in the range of from λto λin longitudinal direction, and a drawing rate of at least 1 m/min to form an oriented film showing stress-whitening, wherein λis the draw ratio at which a transfer from a transparent product to a stress-whitened product occurs and λis the draw ratio at which failure of the stress whitened film occurs; and c) heat-setting the oriented stress-whitened film; the thermoplastic polyester composition substantially consisting of at least one crystallizable polyester derived from at least one aliphatic diol and at least one aromatic dicarboxylic acid. With this process it is possible to make a unitary, glossy, opaque film from a polyester composition that does not contain void-forming additives like high amounts of fine pigment particles or dispersed non-miscible polymer particles. The film obtained also has very good mechanical properties. It is a further advantage that the process can be performed continuously on conventional extrusion and stretching equipment used for making transparent film from polyesters. The invention also relates to an opaque polyester film obtainable by said process.