The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 31, 2017

Filed:

Oct. 29, 2014
Applicant:

International Business Machines Corporation, Armonk, NY (US);

Inventors:

Joy Cheng, Taipei, TW;

Anindarupa Chunder, San Jose, CA (US);

Melia Tjio, San Jose, CA (US);

Ankit Vora, San Jose, CA (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C09D 125/14 (2006.01); G03F 1/00 (2012.01); G03F 7/00 (2006.01); G03F 7/038 (2006.01); C08F 12/22 (2006.01); C08F 212/08 (2006.01); C08F 293/00 (2006.01); C09D 125/18 (2006.01);
U.S. Cl.
CPC ...
C09D 125/14 (2013.01); C08F 12/22 (2013.01); C08F 212/08 (2013.01); C08F 293/005 (2013.01); C09D 125/18 (2013.01); G03F 1/00 (2013.01); G03F 7/0002 (2013.01); G03F 7/038 (2013.01); C08F 2438/01 (2013.01);
Abstract

An orientation control layer (OCL) for self-assembly of block copolymers comprises a random copolymer comprising a first repeat unit having an ethylenic backbone functional group and a side chain aromatic ring, a second repeat unit comprising an ethylenic backbone functional group and a side chain polycarbonate, and a third repeat unit comprising an ethylenic backbone functional group and a side chain ester or amide bearing an active group capable of forming a covalent bond with a substrate surface (e.g., a silicon wafer). The OCLs are neutral wetting to block copolymers having a high Flory-Huggins interaction parameter chi (χ) ('high-chi' block copolymers) such as a block copolymer comprising a polystyrene block and a polycarbonate block. The neutral OCL wetting properties allow for formation of lamellar domain patterns of the self-assembled high-chi block copolymers to be oriented perpendicular to the OCL surface.


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