The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 31, 2017

Filed:

Nov. 24, 2011
Applicants:

Makoto Muranaka, Okayama, JP;

Toshiyuki Oshiki, Okayama, JP;

Inventors:

Makoto Muranaka, Okayama, JP;

Toshiyuki Oshiki, Okayama, JP;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C01B 3/22 (2006.01); B01J 31/20 (2006.01); C07F 15/00 (2006.01); C07C 5/03 (2006.01); C07C 5/09 (2006.01); C07F 15/02 (2006.01); H01M 8/06 (2016.01); B01J 31/24 (2006.01); C07F 9/50 (2006.01);
U.S. Cl.
CPC ...
C07F 15/0033 (2013.01); B01J 31/20 (2013.01); B01J 31/2409 (2013.01); B01J 31/2414 (2013.01); C01B 3/22 (2013.01); C07C 5/03 (2013.01); C07C 5/09 (2013.01); C07F 9/5045 (2013.01); C07F 15/004 (2013.01); C07F 15/008 (2013.01); C07F 15/0053 (2013.01); C07F 15/025 (2013.01); H01M 8/0606 (2013.01); C01B 2203/0277 (2013.01); C01B 2203/1064 (2013.01); C07C 2531/24 (2013.01); Y02E 60/50 (2013.01);
Abstract

Provided is a catalyst for producing hydrogen, which catalyst has higher performance than conventional catalysts since, for example, it exhibits a certain high level of activity in an aqueous formic acid solution at high concentration even without addition of a solvent, amine and/or the like. The metal phosphine complex is a metal phosphine complex represented by General Formula (1): MH(CO)L, wherein M represents an iridium, iron, rhodium or ruthenium atom; in cases where M is an iridium or rhodium atom, m=3 and n=2, and in cases where M is an iron or ruthenium atom, m=2 and n=3; and the number n of Ls each independently represent a tri-substituted phosphine represented by General Formula (2): PRRR. The catalyst for producing hydrogen comprises the metal phosphine complex as a constituent component.


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