The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 31, 2017

Filed:

Mar. 20, 2014
Applicants:

Nutrichem Company Limited, Beijing, CN;

Shangyu Nutrichem Co., Ltd., Zhejiang, CN;

Inventors:

Xufang Deng, Beijing, CN;

Wenjun Wang, Beijing, CN;

Jianwei Chen, Beijing, CN;

Yongchang Zhao, Beijing, CN;

Jianhong Chi, Beijing, CN;

Long Wang, Beijing, CN;

Hua'nan You, Beijing, CN;

Assignees:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 69/618 (2006.01); C07D 239/52 (2006.01); C07C 67/31 (2006.01); C07D 239/34 (2006.01); C07D 213/64 (2006.01); C07C 67/327 (2006.01);
U.S. Cl.
CPC ...
C07D 239/52 (2013.01); C07C 67/31 (2013.01); C07C 67/327 (2013.01); C07D 213/64 (2013.01); C07D 239/34 (2013.01);
Abstract

The present invention relates to a method for preparing an acrylate compound. The acrylate compound has a structure as shown in formula (I). The method includes: subjecting a compound with a structure of formula (II) or a mixture of compounds with structures of formula (I) and formula (II), and a catalyst to a contact reaction in the absence of an anhydride, and removing the resulting methanol by pressure reduced distillation during the contact reaction process. In the formulas (I) and (II), R is selected from one of: an alkoxy with a carbon number of 1-5, a substituent-containing phenoxyl with a carbon number of 6-20, a substituent-containing heteroaryloxy with a carbon number of 4-20, a substituent-containing heteroaryloxymethyl with a carbon number of 4-20, a substituent-containing phenoxymethyl with a carbon number of 5-20, and a substituent-containing alkyl with a carbon number of 2-20. According to the method for preparing an acrylate compound provided in the invention, the conversion rate and selectivity of the reaction can be substantially improved.


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