The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 10, 2017

Filed:

Nov. 27, 2013
Applicant:

Wisconsin Alumni Research Foundation, Madison, WI (US);

Inventors:

Paul Franklin Nealey, Madison, WI (US);

Mark Petar Stoykovich, Dover, NH (US);

Konstantinos C. Daoulas, Goettingen, GB;

Marcus Muller, Goettingen, GB;

Juan J. De Pablo, Madison, WI (US);

SangMin Park, Madison, WI (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B05D 3/06 (2006.01); B32B 3/30 (2006.01); B01D 69/10 (2006.01); B01D 71/80 (2006.01); B81C 1/00 (2006.01); B82Y 30/00 (2011.01); G03F 7/20 (2006.01); B05D 5/00 (2006.01); B01D 71/40 (2006.01);
U.S. Cl.
CPC ...
B32B 3/30 (2013.01); B01D 69/10 (2013.01); B01D 71/80 (2013.01); B05D 5/00 (2013.01); B81C 1/00031 (2013.01); B82Y 30/00 (2013.01); G03F 7/70408 (2013.01); B01D 71/40 (2013.01); B01D 2323/225 (2013.01); B81C 2201/0149 (2013.01); Y10T 428/24322 (2015.01); Y10T 428/24331 (2015.01); Y10T 428/24612 (2015.01); Y10T 428/24802 (2015.01); Y10T 428/269 (2015.01);
Abstract

Methods of fabricating complex three-dimensional structures on patterned substrates and related compositions are provided. The methods involve depositing on the substrate a block copolymer material that is 'mismatched' to the substrate pattern, and then ordering the material to form a complex three-dimensional structure. According to various embodiments, the copolymer material mismatches the substrate pattern in that the symmetry and/or length scale of its bulk morphology differs from that of the pattern. When ordered, a balance between the physics that determines the bulk block copolymer morphology and the physics that determines the substrate surface interfacial interactions results in a thermodynamically stable complex three-dimensional film that varies in a direction perpendicular to the substrate and has a morphology that differs from its bulk morphology.


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