The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 03, 2017

Filed:

Jul. 01, 2015
Applicant:

California Institute of Technology, Pasadena, CA (US);

Inventors:

Guangbin Dong, Austin, TX (US);

Robert H. Grubbs, South Pasadena, CA (US);

Peili Teo, Jurong Island, SG;

Zachary K. Wickens, Pasadena, CA (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/145 (2006.01); C07C 29/143 (2006.01); C07C 29/03 (2006.01); C07C 29/14 (2006.01); C07C 45/30 (2006.01); C07C 201/12 (2006.01);
U.S. Cl.
CPC ...
C07C 29/143 (2013.01); C07C 29/03 (2013.01); C07C 29/14 (2013.01); C07C 45/30 (2013.01); C07C 201/12 (2013.01);
Abstract

The disclosure provides a dual-catalysis system for direct conversion of olefins to alcohols. The cooperative catalytic system contains one oxidizing catalyst and one transfer-hydrogenation catalyst. A wide variety of olefins, including aromatic and aliphatic olefins, can be used as the reactant. The transformation proceeds with anti-Markovnikov selectivity, and in some aspects provides primary alcohols as major products. The disclosure further provides a system for oxidation of olefins with anti-Markovnikov selectivity.


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