The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 27, 2016

Filed:

Sep. 30, 2014
Applicant:

University of Florida Research Foundation, Inc., Gainesville, FL (US);

Inventors:

Eric D. Wachsman, Fulton, MD (US);

Hee Sung Yoon, College Park, MD (US);

Takkeun Oh, Daejeon, KR;

Jianlin Li, Knoxville, TN (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 19/02 (2006.01); C01B 3/02 (2006.01); C01B 3/34 (2006.01); B01D 71/02 (2006.01); B01D 67/00 (2006.01); B01J 19/24 (2006.01); C01B 3/50 (2006.01); C04B 38/00 (2006.01); C04B 41/50 (2006.01);
U.S. Cl.
CPC ...
B01D 71/024 (2013.01); B01D 67/0046 (2013.01); B01J 19/02 (2013.01); B01J 19/2485 (2013.01); C01B 3/02 (2013.01); C01B 3/34 (2013.01); C01B 3/503 (2013.01); C01B 3/505 (2013.01); C04B 38/0038 (2013.01); C04B 41/5027 (2013.01); B01D 2323/20 (2013.01); B01D 2325/00 (2013.01); B01J 2219/00135 (2013.01); B01J 2219/0254 (2013.01); C01B 2203/0283 (2013.01); C01B 2203/041 (2013.01); C01B 2203/0405 (2013.01); C01B 2203/047 (2013.01); C01B 2203/048 (2013.01); C01B 2203/0475 (2013.01); C01B 2203/0495 (2013.01); C01B 2203/1205 (2013.01); C01B 2203/1217 (2013.01); C01B 2203/1235 (2013.01); C01B 2203/86 (2013.01); Y02P 30/30 (2015.11); Y10T 428/24997 (2015.04);
Abstract

In one embodiment, a membrane of proton-electron conducting ceramics that is useful for the conversion of a hydrocarbon and steam to hydrogen has a porous support coated with a film of a Perovskite-type oxide. By including the Zr and M in the oxide in place of Ce, the stability can be improved while maintaining sufficient hydrogen flux for efficient generation of hydrogen. In this manner, the conversion can be carried out by performing steam methane reforming (SMR) and/or water-gas shift reactions (WGS) at high temperature, where the conversion of CO to COand His driven by the removal of Hto give high conversions.


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