The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 20, 2016

Filed:

Nov. 19, 2013
Applicant:

Battelle Memorial Institute, Richland, WA (US);

Inventors:

Tianbiao Liu, Richland, WA (US);

Guosheng Li, Richland, WA (US);

Jun Liu, Richland, WA (US);

Yuyan Shao, Richland, WA (US);

Assignee:

Battelle Memorial Institute, Richland, WA (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
H01M 10/054 (2010.01); H01M 10/0568 (2010.01);
U.S. Cl.
CPC ...
H01M 10/0568 (2013.01); H01M 10/054 (2013.01);
Abstract

Electrolytes for Mg-based energy storage devices can be formed from non-nucleophilic Mgsources to provide outstanding electrochemical performance and improved electrophilic susceptibility compared to electrolytes employing nucleophilic sources. The instant electrolytes are characterized by high oxidation stability (up to 3.4 V vs Mg), improved electrophile compatibility and electrochemical reversibility (up to 100% coulombic efficiency). Synthesis of the Mgelectrolytes utilizes inexpensive and safe magnesium dihalides as non-nucleophilic Mgsources in combination with Lewis acids, MRX(for 3≧a≧1). Furthermore, addition of free-halide-anion donors can improve the coulombic efficiency of Mg electrolytes from nucleophilic or non-nucleophilic Mgsources.


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