The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 13, 2016

Filed:

Jan. 11, 2016
Applicant:

The Chemours Company Fc, Llc, Wilmington, DE (US);

Inventors:

Paul Douglas Brothers, Chadds Ford, PA (US);

Subhash Vishnu Gangal, Hockessin, DE (US);

Dipti Dilip Khasnis, Wilmington, DE (US);

Assignee:

THE CHEMOURS COMPANY FC, LLC, Wilmington, DE (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C08F 2/26 (2006.01); C08F 14/18 (2006.01); C08F 14/26 (2006.01); C08K 5/41 (2006.01); C09D 127/18 (2006.01);
U.S. Cl.
CPC ...
C08K 5/41 (2013.01); C08F 14/18 (2013.01); C08F 14/26 (2013.01); C09D 127/18 (2013.01);
Abstract

A process is provided for the polymerization of fluoromonomer to an dispersion of fluoropolymer particles in an aqueous medium in a polymerization reactor, by (a) providing the aqueous medium in the reactor, (b) adding the fluoromonomer to the reactor, (c) adding initiator to the aqueous medium, the combination of steps (b) and (c) being carried out essentially free of hydrocarbon-containing surfactant and resulting in the kickoff of the polymerization of the fluoromonomer, and (d) metering hydrocarbon-containing surfactant into the aqueous medium after the kickoff of polymerization, e.g. after the concentration of the fluoropolymer in the aqueous medium is at least 0.6 wt %, the metering being at a rate reducing the telogenic activity of said surfactant while maintaining surface activity.


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