The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 29, 2016

Filed:

Aug. 06, 2014
Applicant:

The Scripps Research Institute, La Jolla, CA (US);

Inventors:

Roy A. Periana, Jupiter, FL (US);

Michael M. Konnick, Palm Beach Gardens, FL (US);

Brian G. Hashiguchi, Palm Beach Gardens, FL (US);

Assignee:

The Scripps Research Institute, La Jolla, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/00 (2006.01); C07C 395/00 (2006.01); C07C 1/00 (2006.01); C07C 209/00 (2006.01); C07C 319/00 (2006.01); C07F 7/00 (2006.01); C07C 391/00 (2006.01); C07C 1/32 (2006.01); C07C 319/02 (2006.01); C07C 319/14 (2006.01); C07C 17/093 (2006.01); C07B 39/00 (2006.01); C07B 41/06 (2006.01); C07B 43/04 (2006.01); C07B 45/00 (2006.01); C07B 47/00 (2006.01); C07C 209/22 (2006.01); C07C 231/10 (2006.01); C07F 7/22 (2006.01); C07F 9/50 (2006.01);
U.S. Cl.
CPC ...
C07C 395/00 (2013.01); C07B 39/00 (2013.01); C07B 41/06 (2013.01); C07B 43/04 (2013.01); C07B 45/00 (2013.01); C07B 47/00 (2013.01); C07C 1/321 (2013.01); C07C 17/093 (2013.01); C07C 45/00 (2013.01); C07C 209/22 (2013.01); C07C 231/10 (2013.01); C07C 319/02 (2013.01); C07C 319/14 (2013.01); C07C 391/00 (2013.01); C07F 7/2208 (2013.01); C07F 9/5004 (2013.01);
Abstract

The invention provides processes and materials for the efficient and costeffective functionalization of alkanes and heteroalkanes, comprising contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium, which can be carried out at a temperature of less than 300 C. Isolation of the alkylselenium or alkyltellurium intermediate allows the subsequent conversion to products not necessarily compatible with the initial reaction conditions, such as amines, stannanes, organosulfur compounds, acyls, halocarbons, and olefins.


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