The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 29, 2016

Filed:

Jul. 23, 2015
Applicant:

Total Research & Technology Feluy, Seneffe (Feluy), BE;

Inventors:

Delphine Minoux, Nivelles, BE;

Nikolai Nesterenko, Nivelles, BE;

Cindy Adam, Wierde, BE;

Sander Van Donk, Sainte-Adresse, FR;

Walter Vermeiren, Houthalen, BE;

Assignee:

Total Research & Technology Feluy, Seneffe (Feluy), BE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 1/24 (2006.01); B01J 29/65 (2006.01); B01J 29/90 (2006.01); C23C 18/00 (2006.01); C25D 7/06 (2006.01); C25D 17/00 (2006.01);
U.S. Cl.
CPC ...
C07C 1/24 (2013.01); B01J 29/65 (2013.01); B01J 29/90 (2013.01); C23C 18/00 (2013.01); C25D 7/0664 (2013.01); C25D 17/00 (2013.01); B01J 2229/16 (2013.01); B01J 2229/36 (2013.01); C07C 2529/65 (2013.01); C07C 2529/70 (2013.01); C07C 2529/85 (2013.01); Y02P 20/52 (2015.11); Y02P 20/584 (2015.11);
Abstract

A process for the dehydration of an alcohol having at least 2 carbon atoms to make a corresponding olefin may include introducing in a reactor a stream (A) containing the alcohol, optionally water, and optionally an inert component. The stream (A) may be contacted with a catalyst in the reactor at conditions effective to dehydrate at least a portion of the alcohol to make the corresponding olefin. The process includes recovering from the reactor an olefin containing stream (B). The catalyst may be a crystalline silicate, dealuminated crystalline silicate, or phosphorus modified crystalline silicate, each of the group FER, MWW, EUO, MFS, ZSM-48, MTT or TON having Si/Al ranging from 25 to 90. The weight hourly space velocity (WHSV) of the alcohol may be at least 4 h. The temperature may range from 280° C. to 600° C., or from 320° C. to 600° C.


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