The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 22, 2016

Filed:

Mar. 08, 2012
Applicants:

Arnaud Cadix, Saint-Ouen, FR;

Rabih Rached, Millery, FR;

Pierre Ardaud, Sainte-Foy-les-Lyon, FR;

Inventors:

Arnaud Cadix, Saint-Ouen, FR;

Rabih Rached, Millery, FR;

Pierre Ardaud, Sainte-Foy-les-Lyon, FR;

Assignee:

RHODIA OPERATIONS, Aubervilliers, FR;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C09K 8/00 (2006.01); C08G 18/08 (2006.01); C09D 175/14 (2006.01); C09K 8/508 (2006.01); C09K 8/516 (2006.01); C09K 8/575 (2006.01); C09K 17/18 (2006.01); C09K 17/48 (2006.01); C09K 8/44 (2006.01); E02D 3/12 (2006.01); E02D 37/00 (2006.01); E21B 33/138 (2006.01); E21D 11/38 (2006.01); F16L 55/1645 (2006.01);
U.S. Cl.
CPC ...
C09D 175/14 (2013.01); C09K 8/44 (2013.01); C09K 8/508 (2013.01); C09K 8/516 (2013.01); C09K 8/5751 (2013.01); C09K 17/18 (2013.01); C09K 17/48 (2013.01); E02D 3/12 (2013.01); E02D 37/00 (2013.01); E21B 33/138 (2013.01); E21D 11/38 (2013.01); F16L 55/1645 (2013.01); C09K 2208/14 (2013.01);
Abstract

A process allowing the encapsulation of a polymerization accelerator comprising the steps of: a) providing an reverse emulsion containing, in an oil phase, a water solution/dispersion containing the polymerization activator, the oil phase including a heat curable mixture of an isocyanate and a polyalkyldiene hydroxylated or polyol, b) pouring the reverse emulsion in a water phase to make a multiple emulsion water/oil/water, containing drops of activators as the internal water phase, and then, c) heating the multiple emulsion obtained in step b) at a temperature of between 50 and 95° C., in order to cure the polyisocyanate in polyurethane and obtain drops of activator enclosed in shells of polyurethane dispersed in water. The invention also relates to aqueous gelling systems comprising the encapsulated polymerization accelerator with water soluble or dispersable monomers and a polymerization initiator dispersed in said monomers, useful i.a. for sealing subterranean environments or consolidation of a soil or sealing of a subterranean structure.


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