The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 08, 2016

Filed:

Mar. 18, 2012
Applicants:

Hongchen Guo, Liaoning, CN;

Ji Su, Liaoning, CN;

Guanghong Liu, Liaoning, CN;

Inventors:

Hongchen Guo, Liaoning, CN;

Ji Su, Liaoning, CN;

Guanghong Liu, Liaoning, CN;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C01B 39/08 (2006.01); B01J 29/89 (2006.01); B01J 29/04 (2006.01); C07D 301/03 (2006.01); C07D 303/04 (2006.01); B01J 29/035 (2006.01); C01B 37/00 (2006.01);
U.S. Cl.
CPC ...
B01J 29/041 (2013.01); B01J 29/035 (2013.01); B01J 29/89 (2013.01); C01B 37/005 (2013.01); C01B 39/085 (2013.01); C07D 301/03 (2013.01); C07D 303/04 (2013.01); B01J 2229/183 (2013.01); B01J 2229/34 (2013.01); B01J 2229/38 (2013.01);
Abstract

This invention relates to a modification method for titanium-silicalite zeolite (TS-1). The feature of the invention is pretreating the TS-1, after that the TS-1 is modified by the mixture of quaternary ammonium salts and inorganic base. The quaternary ammonium salts mentioned above include tetrapropylammonium fluoride, tetrapropylammonium chloride, tetrapropylammonium iodide and their mixture. The inorganic base includes LiOH, NaOH and KOH and their mixtures. TS-1 after the modification is aftertreated at last. The invention is universal capable to modify the TS-1 synthesized by any method, especially the TS-1 made with a low cost method. The modification can enhance the catalytic performance on both gas and liquid phase epoxidation of propylene.


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