The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 01, 2016

Filed:

May. 05, 2015
Applicant:

Dioxide Materials, Inc., Champaign, IL (US);

Inventors:

Richard I. Masel, Boca Raton, FL (US);

Qingmei Chen, Savoy, IL (US);

Zengcai Liu, Savoy, IL (US);

Robert Kutz, Champaign, IL (US);

Assignee:

Dioxide Materials, Inc., Boca Raton, FL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C25B 9/08 (2006.01); C25B 13/08 (2006.01); C25B 3/04 (2006.01); B01J 41/14 (2006.01); H01M 8/10 (2016.01);
U.S. Cl.
CPC ...
C25B 9/08 (2013.01); B01J 41/14 (2013.01); C25B 3/04 (2013.01); C25B 13/08 (2013.01); H01M 8/1023 (2013.01); H01M 8/1044 (2013.01); H01M 2300/0082 (2013.01);
Abstract

An electrochemical device converts carbon dioxide to a reaction product. The device includes an anode and a cathode, each comprising a quantity of catalyst. The anode and cathode each has reactant introduced thereto. A polymer electrolyte membrane is interposed between the anode and the cathode. At least a portion of the cathode catalyst is directly exposed to gaseous carbon dioxide during electrolysis. The average current density at the membrane is at least 20 mA/cm, measured as the area of the cathode gas diffusion layer that is covered by catalyst, and CO selectivity is at least 50% at a cell potential of 3.0 V. In some embodiments, the polymer electrolyte membrane comprises a polymer in which a constituent monomer is (p-vinylbenzyl)-R, where R is selected from the group consisting of imidazoliums, pyridiniums and phosphoniums. In some embodiments, the polymer electrolyte membrane is a Helper Membrane comprising a polymer containing an imidazolium ligand, a pyridinium ligand, or a phosphonium ligand.


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