The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Patent No.:

US 9474997 B1

PDF
Full Text
Expired
Date of Patent:
Oct. 25, 2016

Filed:

Mar. 19, 2015
Applicant:

U.s. Army Edgewood Chemical and Biological Command, Washington, DC (US);

Inventors:

Gregory W Peterson, Belcamp, MD (US);

Jared B. DeCoste, Baltimore, MD (US);

Tyler J Demasky, Glen Burnie, MD (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01D 53/04 (2006.01); B01J 20/22 (2006.01); B01J 20/28 (2006.01);
U.S. Cl.
CPC ...
B01D 53/04 (2013.01); B01J 20/226 (2013.01); B01J 20/28092 (2013.01); B01D 2253/204 (2013.01); B01D 2253/308 (2013.01); B01D 2253/31 (2013.01); B01D 2257/2025 (2013.01); B01D 2257/30 (2013.01);
Abstract

This invention is directed to a porous sorbent comprising a modified metal-organic framework (MOF) having a hierarchical pore structure. The MOF is modified by plasma-enhanced chemical vapor deposition with air, fluorocarbons, or other sources of fluorine. In preferred embodiments the MOFs are zirconium based. The modified MOF, while surprisingly retaining its crystal structure, comprises a mixture of micropores and mesopores and embedded fluorine atoms.


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