The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 18, 2016

Filed:

Dec. 19, 2013
Applicant:

Shell Oil Company, Houston, TX (US);

Inventors:

Joseph Broun Powell, Houston, TX (US);

Glenn Charles Komplin, Katy, TX (US);

John Anthony Smegal, Houston, TX (US);

Kimberly Ann Johnson, Richmond, TX (US);

Assignee:

Shell Oil Company, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 1/00 (2006.01); C10L 1/18 (2006.01); B01J 21/04 (2006.01); C10G 1/06 (2006.01); C10G 3/00 (2006.01); B01J 37/20 (2006.01); B01J 23/882 (2006.01); B01J 35/10 (2006.01); B01J 37/02 (2006.01); B01J 23/86 (2006.01); B01J 23/88 (2006.01); B01J 35/00 (2006.01); B01J 35/02 (2006.01);
U.S. Cl.
CPC ...
C10L 1/1802 (2013.01); B01J 21/04 (2013.01); B01J 23/86 (2013.01); B01J 23/88 (2013.01); B01J 23/882 (2013.01); B01J 35/1009 (2013.01); B01J 35/1014 (2013.01); B01J 37/0201 (2013.01); B01J 37/20 (2013.01); C10G 1/065 (2013.01); C10G 3/46 (2013.01); C10G 3/48 (2013.01); C10G 3/50 (2013.01); B01J 35/0046 (2013.01); B01J 35/026 (2013.01); B01J 35/1066 (2013.01); C10G 2300/1014 (2013.01); Y02P 30/20 (2015.11);
Abstract

A method of hydrothermal hydrocatalytic treating biomass is provided. Lignocellulosic biomass solids is provided to a hydrothermal digestion unit in the presence of a digestive solvent, and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into an alumina support, which support is predominantly alpha alumina; (ii) heating the lignocellulosic biomass solids and digestive solvent in the presence of hydrogen, and supported hydrogenolysis catalyst thereby forming a product solution containing plurality of oxygenated hydrocarbons, said alumina support having a specific surface area of up to about 30 m/g and said catalyst retaining a crush strength of at least 50% after being subjected to an aqueous phase stability test compared with before the aqueous phase stability test or a crush strength of at least 0.25 kg after being subjected to an aqueous phase stability test.


Find Patent Forward Citations

Loading…