The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 11, 2016

Filed:

Sep. 08, 2014
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Jihad M. Dakka, Whitehouse Station, NJ (US);

Lorenzo C. DeCaul, Langhorne, PA (US);

Keith H. Kuechler, Friendswood, TX (US);

Neeraj Sangar, League City, TX (US);

Michael Salciccioli, Houston, TX (US);

Alan A. Galuska, Huffman, TX (US);

Gary D. Mohr, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 2/74 (2006.01); C08G 63/185 (2006.01); C08G 63/199 (2006.01); C08J 5/18 (2006.01); D21H 27/20 (2006.01); H01B 3/44 (2006.01); C07C 51/265 (2006.01); C07C 5/367 (2006.01);
U.S. Cl.
CPC ...
C08G 63/185 (2013.01); C07C 2/74 (2013.01); C07C 5/367 (2013.01); C07C 51/265 (2013.01); C08G 63/199 (2013.01); C08J 5/18 (2013.01); D21H 27/20 (2013.01); H01B 3/443 (2013.01); C07C 2101/14 (2013.01); C08J 2327/06 (2013.01); C08K 2201/014 (2013.01); Y10T 428/2964 (2015.01);
Abstract

In a process for producing 3,4' and/or 4,4′ dimethyl-substituted biphenyl compounds, a feed comprising toluene is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes. At least part of the hydroalkylation reaction product is dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of dimethyl-substituted biphenyl isomers. The dehydrogenation reaction product is then separated into at least a first stream containing at least 50% of 3,4′ and 4,4′ dimethylbiphenyl isomers by weight of the first stream and at least one second stream comprising one or more 2,x′ (where x′ is 2′, 3′, or 4′) and 3,3′ dimethylbiphenyl isomers.


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