The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 11, 2016

Filed:

Mar. 13, 2014
Applicant:

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

David G. Barton, Midland, MI (US);

Adam Chojecki, Ghent, BE;

Paul R. Elowe, Midland, MI (US);

Beata A. Kilos, Midland, MI (US);

Adam S. Cieszlak, Bay City, MI (US);

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 41/09 (2006.01); C09K 5/00 (2006.01); B01J 27/125 (2006.01); B01J 37/08 (2006.01); B01J 37/22 (2006.01); B01J 37/24 (2006.01); B01J 23/10 (2006.01); C09K 5/10 (2006.01); B01J 37/03 (2006.01); B01J 27/10 (2006.01); B01J 35/00 (2006.01); B01J 35/10 (2006.01); B01J 27/06 (2006.01); C09K 5/06 (2006.01);
U.S. Cl.
CPC ...
B01J 27/125 (2013.01); B01J 23/10 (2013.01); B01J 27/06 (2013.01); B01J 27/10 (2013.01); B01J 35/002 (2013.01); B01J 35/1009 (2013.01); B01J 35/1038 (2013.01); B01J 37/031 (2013.01); B01J 37/088 (2013.01); B01J 37/22 (2013.01); B01J 37/24 (2013.01); C07C 41/09 (2013.01); C09K 5/063 (2013.01); C09K 5/10 (2013.01);
Abstract

Provided is a process for preparing a diaryl ether compound through the dehydration of an aromatic alcohol compound in the presence of a halogenated rare earth element oxide catalyst, providing a reaction vessel having loaded therein a rare earth element oxide; halogenating the rare earth element oxide with a halogen source to form an activated catalyst; and dehydrating an aromatic alcohol compound over the activated catalyst to form the diaryl ether compound, where the halogenating and dehydrating steps occur in the same vessel. The rare earth element oxide is an oxide of a light rare earth element, an oxide of a medium rare earth element, an oxide of a heavy rare earth element, an oxide of yttrium, or a mixture of two or more thereof.


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