The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Patent No.:

US 9434666 B1

PDF
Full Text
Expired
Date of Patent:
Sep. 06, 2016

Filed:

Aug. 16, 2012
Applicants:

Kalyan V. Vasudevan, Los Alamos, NM (US);

Guoqi Zhang, Los Alamos, NM (US);

Susan K. Hanson, Los Alamos, NM (US);

Inventors:

Kalyan V. Vasudevan, Los Alamos, NM (US);

Guoqi Zhang, Los Alamos, NM (US);

Susan K. Hanson, Los Alamos, NM (US);

Assignee:

Los Alamos National Security, LLC, Los Alamos, NM (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/145 (2006.01); C07C 67/303 (2006.01); C07C 51/36 (2006.01); C07C 41/18 (2006.01); C07C 41/01 (2006.01); C07C 41/20 (2006.01); C07C 45/62 (2006.01); C07C 209/52 (2006.01); C07C 5/03 (2006.01); C07C 5/05 (2006.01); C07C 231/24 (2006.01); C07F 15/04 (2006.01); C07F 15/06 (2006.01); C07F 5/04 (2006.01); C07D 211/46 (2006.01); C07C 29/17 (2006.01); C07C 17/354 (2006.01); C07C 29/141 (2006.01); C07C 41/26 (2006.01); C07D 211/02 (2006.01); B01J 31/18 (2006.01);
U.S. Cl.
CPC ...
C07C 29/172 (2013.01); B01J 31/189 (2013.01); C07C 5/03 (2013.01); C07C 5/05 (2013.01); C07C 17/354 (2013.01); C07C 29/141 (2013.01); C07C 29/145 (2013.01); C07C 29/175 (2013.01); C07C 41/01 (2013.01); C07C 41/18 (2013.01); C07C 41/20 (2013.01); C07C 41/26 (2013.01); C07C 45/62 (2013.01); C07C 51/36 (2013.01); C07C 67/303 (2013.01); C07C 209/52 (2013.01); C07D 211/02 (2013.01); C07D 211/46 (2013.01); C07F 5/04 (2013.01); C07F 15/04 (2013.01); C07F 15/045 (2013.01); C07F 15/06 (2013.01); C07F 15/065 (2013.01); B01J 2231/643 (2013.01); B01J 2531/0244 (2013.01); B01J 2531/845 (2013.01); B01J 2531/847 (2013.01); C07C 2101/14 (2013.01); C07C 2101/16 (2013.01); C07C 2101/18 (2013.01); C07C 2102/08 (2013.01); C07C 2102/42 (2013.01); C07C 2103/18 (2013.01); C07C 2531/14 (2013.01); C07C 2531/28 (2013.01);
Abstract

Complexes of cobalt and nickel with tridentate ligand PNHPare effective for hydrogenation of unsaturated compounds. Cobalt complex [(PNHP)Co(CHSiMe)]BAr(PNHP=bis[2-(dicyclohexylphosphino)ethyl]amine, BAr=B(3,5-(CF)CH))) was prepared and used with hydrogen for hydrogenation of alkenes, aldehydes, ketones, and imines under mild conditions (25-60° C., 1-4 atm H). Nickel complex [(PNHP)Ni(H)]BPhwas used for hydrogenation of styrene and 1-octene under mild conditions. (PNP)Ni(H) was used for hydrogenating alkenes.


Find Patent Forward Citations

Vasudevan, Kalyan. (2016). Catalytic hydrogenation using complexes of base metals with tridentate ligands (U.S. Patent No. 9434666). U.S. Patent and Trademark Office. https://idiyas.com/patent/badge/9434666

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