The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 06, 2016

Filed:

Mar. 27, 2014
Applicant:

Ut-battelle, Llc, Oak Ridge, TN (US);

Inventors:

Christopher J. Janke, Oliver Springs, TN (US);

Sheng Dai, Knoxville, TN (US);

Yatsandra Oyola, Oak Ridge, TN (US);

Assignee:

UT-Battelle, LLC, Oak Ridge, TN (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J 20/26 (2006.01); B01J 20/22 (2006.01); B01J 20/00 (2006.01); C08G 61/04 (2006.01); C08J 3/28 (2006.01); D02G 3/22 (2006.01); D02G 3/34 (2006.01); C08J 7/16 (2006.01); B01J 45/00 (2006.01); B01J 20/28 (2006.01); D06M 10/00 (2006.01); D06M 11/63 (2006.01); D06M 14/28 (2006.01); D06M 15/263 (2006.01); D06M 15/31 (2006.01); C08J 9/36 (2006.01); B01J 20/30 (2006.01); C08J 7/18 (2006.01); C22B 60/02 (2006.01); D06M 101/20 (2006.01);
U.S. Cl.
CPC ...
B01J 20/265 (2013.01); B01J 20/264 (2013.01); B01J 20/28004 (2013.01); B01J 20/28016 (2013.01); B01J 20/28023 (2013.01); B01J 20/28033 (2013.01); B01J 20/3085 (2013.01); B01J 45/00 (2013.01); C08J 3/28 (2013.01); C08J 7/16 (2013.01); C08J 7/18 (2013.01); C08J 9/36 (2013.01); C22B 60/0265 (2013.01); D02G 3/22 (2013.01); D02G 3/34 (2013.01); D06M 10/008 (2013.01); D06M 11/63 (2013.01); D06M 14/28 (2013.01); D06M 15/263 (2013.01); D06M 15/31 (2013.01); C08J 2323/06 (2013.01); C08J 2433/18 (2013.01); D06M 2101/20 (2013.01); Y10T 428/2973 (2015.01); Y10T 428/2978 (2015.01);
Abstract

A fiber-based adsorbent and a related method of manufacture are provided. The fiber-based adsorbent includes polymer fibers with grafted side chains and an increased surface area per unit weight over known fibers to increase the adsorption of dissolved metals, for example uranium, from aqueous solutions. The polymer fibers include a circular morphology in some embodiments, having a mean diameter of less than 15 microns, optionally less than about 1 micron. In other embodiments, the polymer fibers include a non-circular morphology, optionally defining multiple gear-shaped, winged-shaped or lobe-shaped projections along the length of the polymer fibers. A method for forming the fiber-based adsorbents includes irradiating high surface area polymer fibers, grafting with polymerizable reactive monomers, reacting the grafted fibers with hydroxylamine, and conditioning with an alkaline solution. High surface area fiber-based adsorbents formed according to the present method demonstrated a significantly improved uranium adsorption capacity per unit weight over existing adsorbents.


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