The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 02, 2016

Filed:

Oct. 30, 2012
Applicant:

Arkema France, Colombes, FR;

Inventors:

Alain Riondel, Forbach, FR;

Coralie Graire, Grezieu-la-Varenne, FR;

Andre Levray, Procelette, FR;

Reinhard Linemann, Saarbrucken, DE;

Assignee:

Arkema France, Colombes, FR;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 67/08 (2006.01); C07C 67/54 (2006.01); C07C 67/58 (2006.01);
U.S. Cl.
CPC ...
C07C 67/08 (2013.01); C07C 67/54 (2013.01); C07C 67/58 (2013.01); Y02P 20/584 (2015.11);
Abstract

The invention relates to a process for continuously producing 2-octyl acrylate by reacting acrylic acid and 2-octanol in the presence of a sulfonic acid esterification catalyst and at least one polymerization inhibitor. The water formed by the esterification reaction is entrained by distillation in a column surmounting the reactor in the form of a heteroazeotropic mixture with the 2-octanol which is then subjected, after condensation, to separation in a decanter so as to give an upper organic phase and a lower aqueous phase. The reaction mixture containing the reaction product and residual by-products are purified by separation means in order to obtain: (1) pure 2-octyl acrylate and (2) unreacted 2-octanol and acrylic acid compounds that will be recycled along with the catalyst.


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