The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 26, 2016

Filed:

Jul. 14, 2015
Applicant:

Enki Technology, Inc., San Jose, CA (US);

Inventors:

Sina Maghsoodi, San Jose, CA (US);

Brenor L. Brophy, San Jose, CA (US);

Thomas E. Colson, Sunnyvale, CA (US);

Peter R. Gonsalves, Santa Clara, CA (US);

Ze'ev R. Abrams, Mountain View, CA (US);

Assignee:

Enki Technology, Inc., San Jose, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C09D 183/00 (2006.01); C09D 173/00 (2006.01); C09D 5/00 (2006.01); G02B 1/11 (2015.01); C03C 17/30 (2006.01); C09D 183/08 (2006.01); G02B 1/111 (2015.01); G02B 1/12 (2006.01); H01L 31/0216 (2014.01); H01L 31/18 (2006.01); H01L 33/00 (2010.01); H01L 33/44 (2010.01);
U.S. Cl.
CPC ...
C09D 173/00 (2013.01); C03C 17/30 (2013.01); C09D 5/006 (2013.01); C09D 183/08 (2013.01); G02B 1/11 (2013.01); G02B 1/111 (2013.01); G02B 1/12 (2013.01); H01L 31/02168 (2013.01); H01L 31/18 (2013.01); H01L 33/005 (2013.01); H01L 33/44 (2013.01); C03C 2217/20 (2013.01);
Abstract

Disclosed herein are polysilsesquioxane-based anti-reflective coating (ARC) compositions, methods of preparation, and methods of deposition on a substrate. In one embodiment, the polysilsesquioxane of this disclosure is prepared in a two-step process of acid catalyzed hydrolysis of organoalkoxysilane followed by addition of tetralkoxysilane that generates silicone polymers with >40 mol % silanol based on Si-NMR. These high silanol siloxane polymers are stable and have a long shelf-life in polar organic solvents at room temperature. Also disclosed are low refractive index ARC made from these compositions with and without additives such as porogens, templates, thermal radical initiator, photo radical initiators, crosslinkers, Si—OH condensation catalyst and nano-fillers. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes and coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion-resistant functionalized anti-reflective coatings.


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