The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 26, 2016

Filed:

Jun. 24, 2011
Applicants:

Ian Andrew York, Wilton, GB;

Sabina Ziemian, Wilton, GB;

Inventors:

Ian Andrew York, Wilton, GB;

Sabina Ziemian, Wilton, GB;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 27/24 (2006.01); B01J 23/18 (2006.01); B01J 23/20 (2006.01); B01J 27/16 (2006.01); C07C 51/353 (2006.01); C07C 67/343 (2006.01); B01J 27/18 (2006.01); B01J 37/03 (2006.01); C01B 21/097 (2006.01);
U.S. Cl.
CPC ...
B01J 27/24 (2013.01); B01J 23/18 (2013.01); B01J 23/20 (2013.01); B01J 27/16 (2013.01); B01J 27/1811 (2013.01); B01J 27/1813 (2013.01); B01J 37/036 (2013.01); C01B 21/097 (2013.01); C07C 51/353 (2013.01); C07C 67/343 (2013.01);
Abstract

The invention relates to a method of producing an ethylenically unsaturated carboxylic acid or ester, preferably an α, β ethylenically unsaturated carboxylic acid or ester. The method includes contacting formaldehyde or a suitable source thereof with a carboxylic acid or ester in the presence of a catalyst and optionally in the presence of an alcohol. The catalyst comprises a nitrided metal oxide having at least two types of metal cations, Mand M, wherein Mis selected from the metals of group 2, 3, 4, 13 (called also IIIA) or 14 (called also IVA) of the periodic table and M2 is selected from the metals of groups 5 or 15 (called also VA) of the periodic table. The invention extends to a catalyst system.


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