The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 19, 2016

Filed:

Feb. 06, 2014
Applicant:

University of Massachusetts, Boston, MA (US);

Inventors:

Rudolf Faust, Lexington, MA (US);

Ranjan Tripathy, League City, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 110/10 (2006.01); C07D 311/08 (2006.01); C08F 2/48 (2006.01); H01L 51/00 (2006.01); H01L 51/44 (2006.01); H01L 51/52 (2006.01);
U.S. Cl.
CPC ...
C08F 110/10 (2013.01); C07D 311/08 (2013.01); C08F 2/48 (2013.01); H01L 51/004 (2013.01); C08F 2810/40 (2013.01); H01L 51/448 (2013.01); H01L 51/5253 (2013.01);
Abstract

A polyolefin is functionalized with two, three, or more terminal coumarin groups. When irradiated with longer wavelength ultraviolet light (e.g., 365 nanometers), the coumarin groups cyclodimerize to form a chain-extended or crosslinked polyolefin. The cyclodimerization can be reversed by irradiation with shorter wavelength ultraviolet light (e.g., 254 nanometers). When the crosslinked polyolefin is used to form a barrier layer in a light emitting diode or a photovoltaic device, scratches in the barrier layer cleave the cyclodimer groups and can be 'healed' by irradiation to reduce or remove the scratches.


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