The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 21, 2016

Filed:

Apr. 24, 2014
Applicant:

The Texas A&m University System, College Station, TX (US);

Inventors:

David E. Bergbreiter, College Station, TX (US);

Hassan S. Bazzi, Doha, QA;

Chayanant Hongfa, College Station, TX (US);

Assignee:

THE TEXAS A&M UNIVERSITY SYSTEM, College Station, TX (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J 31/16 (2006.01); C07D 207/48 (2006.01); C07D 211/96 (2006.01); C07C 67/30 (2006.01); C07C 67/333 (2006.01); C07D 233/58 (2006.01); C07D 295/24 (2006.01); C07D 403/14 (2006.01); C08L 65/00 (2006.01);
U.S. Cl.
CPC ...
B01J 31/1683 (2013.01); C07C 67/30 (2013.01); C07C 67/333 (2013.01); C07D 207/48 (2013.01); C07D 211/96 (2013.01); C07D 233/58 (2013.01); C07D 295/24 (2013.01); C07D 403/14 (2013.01); C08L 65/00 (2013.01); B01J 2231/543 (2013.01); B01J 2531/17 (2013.01); B01J 2531/821 (2013.01); C07C 2101/10 (2013.01); C07C 2101/16 (2013.01); C08G 2261/418 (2013.01);
Abstract

One embodiment of the invention provides polyisobutylene (PIB) oligormers that are end-functionalized with ruthenium (Ru) catalysts. Such nonpolar catalysts can be dissolved in nonpolar solvents such as heptane, or any other nonpolar solvent that is otherwise not latently biphasic (i.e., if two or more solvent components are present, they remain miscible with each other throughout the entire reaction process, from the addition of substrate through to the removal of product). Substrate that is dissolved in the nonpolar solvent with the catalyst is converted into product. The lower solubility of the product in the nonpolar solvent renders it easily removable, either by extraction with a more polar solvent or by applying physical means in cases where the product precipitates from the nonpolar solvent. In this manner the catalysts are recycled; since the catalysts remain in the nonpolar solvent, a new reaction can be initiated simply by dissolving fresh substrate into the nonpolar solvent.


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