The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 14, 2016

Filed:

Aug. 04, 2014
Applicant:

Bridgestone Corporation, Tokyo, JP;

Inventors:

William L. Hergenrother, Akron, OH (US);

Walter Tomaszewski, Canton, OH (US);

Ashley Hilton, Massillon, OH (US);

Michael Hayes, Canton, OH (US);

James H. Pawlow, Akron, OH (US);

Terrence E. Hogan, Akron, OH (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C08G 77/28 (2006.01); C08L 21/00 (2006.01); B60C 1/00 (2006.01); C08K 7/06 (2006.01); C08G 77/26 (2006.01); C09D 183/08 (2006.01); B29D 30/38 (2006.01); C09J 183/08 (2006.01); D07B 1/06 (2006.01); B29D 30/48 (2006.01); B29C 65/00 (2006.01);
U.S. Cl.
CPC ...
C08K 7/06 (2013.01); B29D 30/38 (2013.01); B60C 1/00 (2013.01); C08G 77/26 (2013.01); C08G 77/28 (2013.01); C08L 21/00 (2013.01); C09D 183/08 (2013.01); C09J 183/08 (2013.01); D07B 1/0666 (2013.01); B29C 66/71 (2013.01); B29C 66/74283 (2013.01); B29D 2030/383 (2013.01); B29D 2030/483 (2013.01); B60C 2009/0014 (2013.04); B60C 2009/0021 (2013.04); Y10T 428/31663 (2015.04);
Abstract

Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water.


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