The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 14, 2016

Filed:

Oct. 17, 2013
Applicants:

Jean-luc Dubois, Millery, FR;

Mickaël Capron, Bachy, FR;

Franck Dumeignil, Fretin, FR;

Inventors:

Jean-Luc Dubois, Millery, FR;

Mickaël Capron, Bachy, FR;

Franck Dumeignil, Fretin, FR;

Assignee:

Arkema France, Colombes, FR;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/38 (2006.01); C07C 45/75 (2006.01);
U.S. Cl.
CPC ...
C07C 45/38 (2013.01); C07C 45/75 (2013.01);
Abstract

The present invention concerns a method for directly synthesizing acrolein or methacrolein from a mixture of methanol and ethanol or propanol. The method of the invention comprises two successive phases: oxidation in the presence of a selective oxidation catalyst of the light alcohols of the feedstock, then condensation by aldolization of the aldehydes formed during oxidation in the presence of a condensation catalyst (aldolization). Alternatively, the two phases can be carried out in the presence of a single catalyst, in particular in the presence of a molybdenum-based selective oxidation catalyst. These two phases can be conducted in a single reactor or in two cascade reactors.


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