The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 14, 2016

Filed:

Mar. 06, 2014
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Gabor Kiss, Hampton, NJ (US);

Thomas E. Green, Hamilton, NJ (US);

Terry E. Helton, Montgomery, TX (US);

William C. Horn, Long Valley, NJ (US);

William A. Lamberti, Stewartsville, NJ (US);

Tan-Jen Chen, Kingwood, TX (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/66 (2006.01); B01J 29/74 (2006.01); B01J 23/44 (2006.01); C07C 2/74 (2006.01); C07C 37/08 (2006.01); C07C 45/53 (2006.01); C07C 407/00 (2006.01); B01J 29/03 (2006.01); B01J 35/02 (2006.01); B01J 35/10 (2006.01); B01J 29/70 (2006.01); B01J 35/00 (2006.01); B01J 29/76 (2006.01);
U.S. Cl.
CPC ...
B01J 29/7476 (2013.01); B01J 23/44 (2013.01); B01J 29/0325 (2013.01); B01J 29/0333 (2013.01); B01J 29/7038 (2013.01); B01J 29/7676 (2013.01); B01J 35/0006 (2013.01); B01J 35/0073 (2013.01); B01J 35/023 (2013.01); B01J 35/1019 (2013.01); C07C 2/74 (2013.01); C07C 37/08 (2013.01); C07C 45/53 (2013.01); C07C 407/00 (2013.01); B01J 35/026 (2013.01); B01J 2229/20 (2013.01); B01J 2229/42 (2013.01); C07C 2/66 (2013.01); C07C 2101/14 (2013.01); C07C 2521/04 (2013.01); C07C 2521/06 (2013.01); C07C 2521/08 (2013.01); C07C 2523/44 (2013.01); C07C 2529/70 (2013.01); C07C 2529/74 (2013.01); Y02P 20/52 (2015.11);
Abstract

A process for producing an alkylated aromatic compound comprises contacting an aromatic starting material and hydrogen with a plurality of catalyst particles under hydroalkylation conditions to produce an effluent comprising the alkylated aromatic compound, the catalyst comprising a composite of a solid acid, an inorganic oxide different from the solid acid and a hydrogenation metal, wherein the distribution of the hydrogenation metal in at least 60 wt % of the catalyst particles is such that the average concentration of the hydrogenation metal in the rim portion of a given catalyst particle is Crim, the average concentration of the hydrogenation metal in the center portion of the given catalyst particle is Ccenter, where 0.2≦Crim/Ccenter<2.0. Also disclosed are hydroalkylation catalyst and process for making phenol and/or cyclohexanone using the catalyst.


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